Electrochemical Generation of Hypervalent Bromine(III) Compounds
نویسندگان
چکیده
منابع مشابه
Pseudopotential Scf-mo Studies of Hypervalent Compounds
The (ab initio) effective potential method developed previously has been applied to several molecules in order to establish a basis set and effective potential for iodine and to examine aspects of the potential surfaces of hypervalent compounds of iodine. Implied lone-pair stereochemical activity is found to agree well with experiment. Results for the structures and force constants closely rese...
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The first representatives of the radical anions of silatranes XSi(OCH2CH2)3N – organic derivatives of the pentacoordinate silicon atom (X = Ph, 1; p-NO2PhO, 2a; m-NO2PhO, 2b; o-NO2PhO, 2c) – were obtained and characterized by EPR spectroscopy. The structure of 1(−˙), 2a(−˙), 2b(−˙), and 2c(−˙) in polar solvents (C-PCM and COSMO models) was studied at the UMP2 and UB3PW91 levels of theory. The v...
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The electrochemical behaviour of indole and a group of indole-containing compounds with a substituent at the C3 position, indol-3-acetamide (IAM), tryptamine, gramine, indole acetic acid (IAA), indole propionic acid (IPA), indole butyric acid (IBA) and tryptophan, was investigated at a glassy carbon electrode, in order to determine their oxidation pathways. Indole undergoes one irreversible pH ...
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: 0044-8249,1521-3757
DOI: 10.1002/ange.202104677